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You need to get a DVD Converter like Nero or something else. I am guessing that you have the movie in Mp3 format or something. You need to burn it into DVD format that will allow you to insert an auto play option or select chapters.
A DVD Ripper can help you do that. Try Tenorshare DVD Ripper. it can help you make DVD disc that can be played in a PS2 console. Here you can see its step-to-step tutorial about how to convert DVD for PS2 [link removed]
My son's PS2 plays burnt discs. I burn off discs using either Nero, Power Producer or Window Movie Maker. Most of what I burn off are in AVI format.